✦ LIBER ✦

Chemistry of geminal-dithiolates derived from cyano-substituted tetrathiafulvalenes

✍ Scribed by Edward M. Engler; Vishnu V. Patel; Robert R. Schumaker

Book ID: 104244385
Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 188 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)93270-8

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✦ Synopsis

Tetracyanotetrathiafulvalene reacts with two equivalents of thiol salts (RS-) to give 1,2-dicyano-1,2-di RS ethene and a geminal dithiolate intermediate which reacts with a variety of reagents to provide novel tetrathioethene derivatives, such as reaction with 3-chloro-2-butanone and acid to give dimethyldicyanotetrathiafulvalene.

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