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Polyacetyl-substituted tetrathiafulvalenes and 1,3-dithiolic derivatives from hex-3-yn-2,5-dione

✍ Scribed by P. Leriche; A. Belyasmine; M. Sallé; P. Frère; A. Gorgues; A. Riou; M. Jubault; J. Orduna; J. Garín

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
297 KB
Volume
37
Category
Article
ISSN
0040-4039

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✦ Synopsis

The cycloaddition of hex-3-yn-2,5-dione onto a rc-CS2 Iron complex 3 and on 3-thioxo-1.2dithioles affords diietylated intermediates which can be readily converted into di or tetraacetylated derivatives of the 1,3-dithiole (5,6) and tetrathiafulvalene (2.8) series, some represemative electrochemical and structural features of which being also presented.

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