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ChemInform Abstract: The Total Synthesis of Scytophycin C. Part 1. Stereocontrolled Synthesis of the C1—C32 Protected Seco Acid.

✍ Scribed by I. PATERSON; K.-S. YEUNG; C. WATSON; R. A. WARD; P. A. WALLACE

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

The Total Synthesis of Scytophycin C. Part 1. Stereocontrolled Synthesis of the C 1 -C 32 Protected Seco Acid.

-A stereocontrolled preparation of the C 1 -C 32 -seco acid ester (XI) required for the total synthesis of the macrolide scytophycin C is presented starting from the aldehyde (S)-(II) in 18% yield and 85% diastereoselectivity. -(

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