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ChemInform Abstract: Toward the Total Synthesis of Hygrolidin: Stereocontrolled Construction of the C1-C17 Seco-Acid Fragment (I) and the C18-C25 (II) Masked Hemiacetal Subunit.

✍ Scribed by K. MAKINO; K. KIMURA; N. NAKAJIMA; S. HASHIMOTO; O. YONEMITSU


Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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ChemInform Abstract: The Total Synthesis
✍ I. PATERSON; K.-S. YEUNG; C. WATSON; R. A. WARD; P. A. WALLACE πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 36 KB πŸ‘ 1 views

The Total Synthesis of Scytophycin C. Part 1. Stereocontrolled Synthesis of the C 1 -C 32 Protected Seco Acid. -A stereocontrolled preparation of the C 1 -C 32 -seco acid ester (XI) required for the total synthesis of the macrolide scytophycin C is presented starting from the aldehyde (S)-(II) in 1