ChemInform Abstract: Synthesis of α,β-Unsaturated Ketones by Pd-Catalyzed Decarboxylative Allylation of α-Oxocarboxylates.
✍ Scribed by Nuria Rodriguez; Filipe Manjolinho; Matthias F. Gruenberg; Lukas J. Goossen
- Book ID
- 112043934
- Publisher
- John Wiley and Sons
- Year
- 2012
- Weight
- 46 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
The experiments in Table 2 were carried out on a 1.00-mmol scale in 20-mL septum-capped vessels. The products were purified by column chromatography (SiO 2 , hexane/ethyl acetate gradient) after aqueous workup.
Lipase-Catalyzed Kinetic Resolution of α,β-Unsaturated α'-Acetoxy Ketones. -The first general, preparative scale procedure for the lipasecatalyzed kinetic resolution of the title compounds providing enantiomerically pure α-acetoxy-and α-hydroxy ketones is presented. The lower e.e. values observed f