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ChemInform Abstract: Rearrangement of Bis((2,4,6-Trimethylphenyl)methanoyl)bicyclo(2.2.1) hept-5-enes to 2-Oxabicyclo(3.3.0)octa-3,7-dienes.

✍ Scribed by F. FREEMAN; J. D. KIM; M. Y. LEE; X. WANG


Book ID
112035233
Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
27
Category
Article
ISSN
0931-7597

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Rearrangement of a Bicyclo[3.2.0]hept-2-
✍ Behrendt, Uwe ;Gabor, Barbara ;Mynott, Richard ;ButenschΓΆn, Holger πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 996 KB

## Abstract The chemistry of the highly substituted cyclobutanone derivative 2, which is easily accessible from 1, is dominated by the steric hindrance caused by the substitutents: Reduction with hydride reagents and nucleophilic additions with methyllithium are less stereoselective than correspond