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Rearrangement of bis[(2, 4, 6-trimethylphenyl)methanoyl]bicyclo[2.2.1]hept-5-enes to 2-oxabicyclo[3.3.0]octa-3, 7-dienes

✍ Scribed by Fillmore Freeman; Jeong Doo Kim; Mark Yun Lee; Xiaojing Wang

Book ID
107857824
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
334 KB
Volume
52
Category
Article
ISSN
0040-4020

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## Abstract The chemistry of the highly substituted cyclobutanone derivative 2, which is easily accessible from 1, is dominated by the steric hindrance caused by the substitutents: Reduction with hydride reagents and nucleophilic additions with methyllithium are less stereoselective than correspond