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A novel rearrangement of tricyclo[4.2.2.02,5]deca-3,7-dien-9-ones to functionalized bicyclo[3.2.1]octa-2,6-dienes

✍ Scribed by Mehta, Goverdhan; Srikrishna, A.


Book ID
126440461
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
460 KB
Volume
46
Category
Article
ISSN
0022-3263

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Novel skeletal rearrangement in addition
✍ Nicolai S. Zefirov; V.N. Kirin; A.S. Kozmin; I.V. Bodrikov; K.A. Potekhin; E.N. πŸ“‚ Article πŸ“… 1979 πŸ› Elsevier Science 🌐 French βš– 206 KB

The "doping-a,-Jdition" of RSCl to the tricyclo[4,2,2,0 2,51 ~deca-3,7-diene derivatives which are incapable of lactone ring closure proceeds to give the 'love1 type of rec3rranged product, x, due to the two subsequent 1,2-shifts.