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ChemInform Abstract: Radical Homologation of D-Gluconic Acid: Highly Diastereoselective Synthesis of D-gluco-KDO Derivatives.

โœ Scribed by Derek H. R. Barton; Mauro V. De Almeida; Wansheng Liu; Tetsuro Shinada; Joseph Cs. Jaszberenyi; Helio F. Dos Santos; Mireille Le Hyaric


Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Silicon-Mediated
โœ Nico Braeuer; Andreas Kirschning; Ernst Schaumann ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB ๐Ÿ‘ 2 views

A Silicon-Mediated Synthesis of 3-Deoxy-D-manno-octulosonic Acid (KDO). -Starting from commercially available D-mannitol (I), the synthesis of KDO ammonium salt (VII) includes, as key steps, a silicon-mediated epoxide ring opening reaction of (II) and silicon-induced lactonization of carbonate (V) w