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ChemInform Abstract: Highly Diastereoselective Radical Addition to Oxime Ethers: Asymmetric Synthesis of β-Amino Acids.

✍ Scribed by Hideto Miyabe; Kayoko Fujii; Takeaki Naito

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: A Concise Synthesis
ChemInform Abstract: A Concise Synthesis of Rigidified β-Amino Acids via Sulfanyl Radical Addition-Cyclization of Oxime Ethers and Hydrazones.
✍ O. MIYATA; K. MUROYA; J. KOIDE; T. NAITO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB

A Concise Synthesis of Rigidified β-Amino Acids via Sulfanyl Radical Addition-Cyclization of Oxime Ethers and Hydrazones. -Sulfanyl radical cyclization of alkenyl-tethered oxime ethers and hydrazones (I) provides cis/trans mixtures of the cyclized products (III) and (IV). The cyclopentylamines (III