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ChemInform Abstract: Plant Bioregulators. Part 2. Syntheses of (.+-.)- and (+)-Sorgolactone, the Germination Stimulant from Sorghum bicolor.

โœ Scribed by Junichi Matsui; Masahiko Bando; Masaru Kido; Yasutomo Takeuchi; Kenji Mori


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
30
Category
Article
ISSN
0931-7597

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Syntheses of (ยฑ)- and (+)-Sorgolactone,
โœ Junichi Matsui; Masahiko Bando; Masaru Kido; Yasutomo Takeuchi; Kenji Mori ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 340 KB ๐Ÿ‘ 2 views

2a, we first synthesized (ยฑ)-2a and its three racemic stereosity of Tokyo, isomers (ยฑ)-2b, (ยฑ)-2c and (ยฑ)-2d as outlined in Scheme 1.

ChemInform Abstract: Synthesis of (3aR,8
โœ K. MORI; J. MATSUI ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB ๐Ÿ‘ 1 views

Synthesis of (3aR,8S,8bS,2'R)-(+)-Sorgolactone and Its Stereoisomers, the Germination Stimulant from Sorghum bicolor. -The total synthesis of the title compound (IX) or its stereoisomers [cf. (X)] is based on the radical cyclization of the methyl (S)-citronellate derived phenylselenylated ester (II