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ChemInform Abstract: Synthesis of (3aR,8S,8bS,2′R)-(+)-Sorgolactone and Its Stereoisomers, the Germination Stimulant from Sorghum bicolor.

✍ Scribed by K. MORI; J. MATSUI

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199806255

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✦ Synopsis

Synthesis of (3aR,8S,8bS,2'R)-(+)-Sorgolactone and Its Stereoisomers, the Germination Stimulant from Sorghum bicolor.

-The total synthesis of the title compound (IX) or its stereoisomers [cf. (X)] is based on the radical cyclization of the methyl (S)-citronellate derived phenylselenylated ester (II). -(MORI, K.; MATSUI,

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