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ChemInform Abstract: Synthesis and Biological Evaluation of the Four Racemic Stereoisomers of the Structure Proposed for Sorgolactone (I), the Germination Stimulant from Sorghum bicolor.

โœ Scribed by K. MORI; J. MATSUI; M. BANDO; M. KIDO; Y. TAKEUCHI


Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Synthesis of (3aR,8
โœ K. MORI; J. MATSUI ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 33 KB

Synthesis of (3aR,8S,8bS,2'R)-(+)-Sorgolactone and Its Stereoisomers, the Germination Stimulant from Sorghum bicolor. -The total synthesis of the title compound (IX) or its stereoisomers [cf. (X)] is based on the radical cyclization of the methyl (S)-citronellate derived phenylselenylated ester (II