ChemInform Abstract: Plant Bioregulators. Part 5. Synthesis of (+)-Strigol and (+)-Orobanchol, the Germination Stimulants, and Their Stereoisomers by Employing Lipase-Catalyzed Asymmetric Acetylation as the Key Step.

Synthesis of (+)-Strigol and (+)-Orobanc

Synthesis of (+)-Strigol and (+)-Orobanchol, the Germination Stimulants, and Their Stereoisomers by Employing Lipase-Catalyzed Asymmetric Acetylationas the Key Step

✍ Kouichi Hirayama; Kenji Mori 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 241 KB 👁 2 views

The potent seed germination stimulants (+)-strigol (1), (+)-2Ј-bisepiorobanchol (2ЈЈЈ)] were prepared from the enantiomers of 3, which were obtainable by lipase-catalyzed orobanchol (2) and their stereoisomers [2Ј-epistrigol (1Ј), ent-1, ent-1Ј, 2Ј-epiorobanchol (2Ј), 4-epiorobanchol (2ЈЈ) and 4, en