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ChemInform Abstract: Pheromone Synthesis. Part 171. A New Synthesis of (2E,4E,6R,10R)-4,6, 10,12-Tetramethyl-2,4-tridecadien-7-one (Matsuone), the Primary Component of the Sex Pheromone of Three Matsucoccus Pine Bast Scales.

✍ Scribed by K. MORI; T. FURUUCHI; K. MATSUYAMA

Book ID
112030044
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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Pheromone synthesis, CLXXI. A new synthe
Pheromone synthesis, CLXXI. A new synthesis of (2E,4E,6R10R)-4,6,10,12-tetramethyl-2,4-tridecadien-7-one (matsuone), the primary component of the sex pheromone of threeMatsucoccus pine bast scales
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## Abstract A new synthesis of (2__E__,4__E__,6__R__,10__R__)‐4,6,10,12‐tetramethyl‐2,4‐tridecadien‐7‐one (1; matsuone) was achieved by starting from (2__R__,3__S__)‐4‐(__tert__‐butyldiphenylsilyloxy)‐2,3‐epoxy‐1‐butanol (21 = E) and methyl (__R__)‐3‐hydroxy‐2‐methylpropanoate (2 = I). Cleavage of

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The sex pheromone of Matsucoccus matsumurae Japanese pine bast scale (2E,4E)-(6R,10R)-4,6,10,12-tetramethyl-2,4-tridecadien-7-one (1) was synthesized with stereocontrol from (2R,4S)-5-acetoxy-2,4-dimethyl-pentanol (3), which in turn was prepared by lipase-catalyzed transesterification of meso-2,4-di

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## Abstract Faranal (1), the trail‐following pheromone of the worker of Pharaoh's ant (__Monomorium pharaonis__), was synthesized by the coupling reaction of the iododiene 3 with the chiral building block 8 as the key step. The geometrically pure iododiene 3 was prepared by the zirconocene‐mediated

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## Abstract (3__S__,7__R__,8__E__,10__E__)‐3,7,9‐Trimethyl‐8,10‐dodecadien‐6‐one (1), the major component of the female‐produced sex pheromone of the maritime pine scale (__Matsucoccus feytaudi__), was synthesized by starting from epoxide 2, which was obtained from __meso__‐__epoxy__ diacetate (F)