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Pheromone synthesis, CLXX. A new synthesis of faranal [(3S,4R,6E,10Z)-3,4,7,11-tetramethyl-6,10-tridecadienal], the trail pheromone of the pharaoh's ant,Monomorium pharaonis

✍ Scribed by Mori, Kenji ;Murata, Noriaki

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
352 KB
Volume
1995
Category
Article
ISSN
0947-3440

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✦ Synopsis

Abstract

Faranal (1), the trail‐following pheromone of the worker of Pharaoh's ant (Monomorium pharaonis), was synthesized by the coupling reaction of the iododiene 3 with the chiral building block 8 as the key step. The geometrically pure iododiene 3 was prepared by the zirconocene‐mediated carboalumination reaction of 2 followed by treatment with iodine.

📜 SIMILAR VOLUMES

Pheromone Synthesis, CLXV. A New Synthes
Pheromone Synthesis, CLXV. A New Synthesis of (3S,7R,8E,10E)-3,7,9-Trimethyl-8,10-dodecadien-6-one, the Major Component of the Sex Pheromone of the Maritime Pine Scale
✍ Mori, Kenji ;Furuuchi, Takeshi ;Kiyota, Hiromasa 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 English ⚖ 416 KB

## Abstract (3__S__,7__R__,8__E__,10__E__)‐3,7,9‐Trimethyl‐8,10‐dodecadien‐6‐one (1), the major component of the female‐produced sex pheromone of the maritime pine scale (__Matsucoccus feytaudi__), was synthesized by starting from epoxide 2, which was obtained from __meso__‐__epoxy__ diacetate (F)