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Synthesis and bioassay of all four stereoisomers of (2E,4E)-4,6,10,12-tetramethyl-2,4-tridecadien-7-one, the assignment of the absolute configuration of the sex pheromone of Matsucoccus matsumurae Japanese pine bast scale

✍ Scribed by Guo-Qiang Lin; Wei-Chu Xu; Yun-Tai Qi; Guo-Min Chen

Book ID
112060299
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
485 KB
Volume
13
Category
Article
ISSN
0256-7660

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Enzymatic synthesis of (2E,4E)-(6R,10R)-
Enzymatic synthesis of (2E,4E)-(6R,10R)-4,6,10,12-tetramethyl-2,4-tridecadien-7-one, the sex pheromone of Matsucoccus matsumurae Japanese pine bast scale
✍ Guo-Qiang Lin; Wei-Chu Xu 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 589 KB

The sex pheromone of Matsucoccus matsumurae Japanese pine bast scale (2E,4E)-(6R,10R)-4,6,10,12-tetramethyl-2,4-tridecadien-7-one (1) was synthesized with stereocontrol from (2R,4S)-5-acetoxy-2,4-dimethyl-pentanol (3), which in turn was prepared by lipase-catalyzed transesterification of meso-2,4-di

Pheromone synthesis, CLXXI. A new synthe
Pheromone synthesis, CLXXI. A new synthesis of (2E,4E,6R10R)-4,6,10,12-tetramethyl-2,4-tridecadien-7-one (matsuone), the primary component of the sex pheromone of threeMatsucoccus pine bast scales
✍ Mori, Kenji ;Furuuchi, Takeshi ;Matsuyama, Keisuke 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 797 KB

## Abstract A new synthesis of (2__E__,4__E__,6__R__,10__R__)‐4,6,10,12‐tetramethyl‐2,4‐tridecadien‐7‐one (1; matsuone) was achieved by starting from (2__R__,3__S__)‐4‐(__tert__‐butyldiphenylsilyloxy)‐2,3‐epoxy‐1‐butanol (21 = E) and methyl (__R__)‐3‐hydroxy‐2‐methylpropanoate (2 = I). Cleavage of