ChemInform Abstract: Palladium-Catalyzed Asymmetric Allylic Substitution Reactions Using New Chiral Phosphinite—Oxazoline Ligands Derived from D-Glucosamine.
✍ Scribed by Koji Yonehara; Tomohiro Hashizume; Kenji Mori; Kouichi Ohe; Sakae Uemura
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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reactions of 1,3diphenyl-2-propenyl acetate (II). Best results are obtained with derivative (Ia). Dimethyl malonate as nucleophile gives the product (IV) with high e.e., whereas benzylamine provides only moderate stereoselectivity. -(JIN, MYUNG-