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ChemInform Abstract: Palladium-Catalyzed Asymmetric Allylic Nucleophilic Substitution Reactions Using Chiral tert-Butanesulfinylphosphine Ligands.

✍ Scribed by Junmin Chen; Feng Lang; Dong Li; Linfeng Cun; Jin Zhu; Jingen Deng; Jian Liao

Publisher
John Wiley and Sons
Year
2010
Weight
40 KB
Volume
41
Category
Article
ISSN
0931-7597

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reactions of 1,3diphenyl-2-propenyl acetate (II). Best results are obtained with derivative (Ia). Dimethyl malonate as nucleophile gives the product (IV) with high e.e., whereas benzylamine provides only moderate stereoselectivity. -(JIN, MYUNG-