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ChemInform Abstract: Organometallic Compounds of the Lanthanoids. Part 129. Synthesis, Structure and Hydrolysis of “Moderately Stable” Hydrosilylation Catalysts [(η5-C5H4SiMe3) 2Ln(μ-Me)]2 and [(η5-C5H4SiMe2tBu) 2Ln(μ-Me)]2.

✍ Scribed by Herbert Schumann; Markus R. Keitsch; Joerg Demtschuk; Gary A. Molander

Publisher
John Wiley and Sons
Year
2010
Weight
41 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Organometallic Compounds of the Lanthanoids. Part 129. Synthesis, Structure and Hydrolysis of "Moderately Stable" Hydrosilylation Catalysts [(η 5 -C 5 H 4 SiMe 3 ) 2 Ln(µ-Me

📜 SIMILAR VOLUMES

Organometallic Compounds of the Lanthani
Organometallic Compounds of the Lanthanides. 127 [1] Synthesis of Monomeric Bis(cyclopentadienyl)lanthanide Tetrahydroborates with Bulky Cyclopentadienyl Ligands. Single Crystal X-ray Structures of [(η5-C5Me5)2SmBH4(THF)] and [(η5-C5Me4Et)2Y(μ-H)2BH2(THF)]
✍ Herbert Schumann; Markus R. Keitsch; Jörg Demtschuk; Stefan Mühle 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 171 KB 👁 2 views

The trichlorides of yttrium, samarium, and lutetium react with 2 equivalents of Na[C 5 H 4 t Bu] and 1 equivalent of NaBH 4 to give [(g 5 -C 5 H 4 t Bu) 2 LnBH 4 (THF)] (Ln = Y (1), Sm (2), Lu (3)) or with 2 equivalents of Na[C 5 Me 4 R] and 1 equivalent of NaBH 4 to form [(g 5 -C 5 Me 4 R) 2 ĹnBH 4