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ChemInform Abstract: New Enantioselective Approach to the Total Synthesis of (-)-α-Kainic Acid.

✍ Scribed by A. RUBIO; J. EZQUERRA; A. ESCRIBANO; M. J. REMUINAN; J. J. VAQUERO

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric Total Sy
ChemInform Abstract: Asymmetric Total Synthesis of (-)-α-Kainic Acid Using an Enantioselective, Metal-Promoted Ene Cyclization.
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ChemInform Abstract: A Formal Synthesis
ChemInform Abstract: A Formal Synthesis of (-)-α-Kainic Acid.
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A Formal Synthesis of (-)-α-Kainic Acid. -Starting from Lpyroglutamic acid (-)-(I), the known precursor (-)-(XVI) for the synthesis of the title compound is presented. The key step in this approach is the SmI 2 -mediated ketyl radical cyclization of the enecarbamate (X). Under irradiation condition