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ChemInform Abstract: Enantioselective Total Synthesis of (-)-α-Kainic Acid

✍ Scribed by M. D. BAICHI; A. MELMAN

Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric Total Sy
ChemInform Abstract: Asymmetric Total Synthesis of (-)-α-Kainic Acid Using an Enantioselective, Metal-Promoted Ene Cyclization.
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

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A Formal Synthesis of (-)-α-Kainic Acid. -Starting from Lpyroglutamic acid (-)-(I), the known precursor (-)-(XVI) for the synthesis of the title compound is presented. The key step in this approach is the SmI 2 -mediated ketyl radical cyclization of the enecarbamate (X). Under irradiation condition