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ChemInform Abstract: Enantioselective Total Synthesis of (-)-α-Kainic Acid Through Free Radical Cyclization of an Alkenyl Monothioformimide.

✍ Scribed by M. D. BACHI; A. MELMAN

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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Stereoselective Synthesis of (±)-α-Kainic Acid Using Free Radical Key Reactions. -The title compound (XI) is obtained via two routes from the highly substituted isocyanide and the isothiocyanate (XII) via the common intermediate (IX). In both routes the key synthons (cf. (IV) and (XIV)) are obtained