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ChemInform Abstract: Nazarov Cyclization of Bis([2.2]paracyclophane-1,9-dienyl) Ketone: First Synthesis of a Bis([2.2]paracyclophane)-Anellated Cyclopenta-1,4-diene.

✍ Scribed by H. A. BUCHHOLZ; A. DE MEIJERE

Publisher: John Wiley and Sons
Year: 2010
Weight: 28 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199911109

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✦ Synopsis

Nazarov Cyclization of Bis ([2.2]paracyclophane-1,9-dienyl) Ketone: First Synthesis of a Bis([2.2]paracyclophane)-Anellated Cyclopenta-1,4-diene.

-The anellated cyclopentanone derivatives (II) and (III) can be obtained by Nazarov cyclization of the ketone (I). (III) is successfully transformed into the cyclopenta-1,4-diene (IV) which is a potential ligand for metallocene complexes. -(BUCHHOLZ, H. A.;

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