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Nazarov Cyclization of Bis([2.2]paracyclophane-1,9-dienyl) Ketone: First Synthesis of a Bis([2.2]paracyclophane)-Annelated Cyclopenta-1,4-diene

✍ Scribed by Herwig A. Buchholz; Armin de Meijere


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
156 KB
Volume
1998
Category
Article
ISSN
1434-193X

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ChemInform Abstract: Nazarov Cyclization
✍ H. A. BUCHHOLZ; A. DE MEIJERE 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB

Nazarov Cyclization of Bis ([2.2]paracyclophane-1,9-dienyl) Ketone: First Synthesis of a Bis([2.2]paracyclophane)-Anellated Cyclopenta-1,4-diene. -The anellated cyclopentanone derivatives (II) and (III) can be obtained by Nazarov cyclization of the ketone (I). (III) is successfully transformed into