𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: The First Synthesis and Characterization of Both Diastereomers of a Di[2.2]paracyclophane: 4,4′-Bis(1,1,2,2,9,9,10,10-octafluoro[2.2]paracyclophane).

✍ Scribed by A. J. Roche; J.-X. Duan; W. R. Dolbier Jr.; K. A. Abboud

Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
33
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

ChemInform Abstract: Nazarov Cyclization
ChemInform Abstract: Nazarov Cyclization of Bis([2.2]paracyclophane-1,9-dienyl) Ketone: First Synthesis of a Bis([2.2]paracyclophane)-Anellated Cyclopenta-1,4-diene.
✍ H. A. BUCHHOLZ; A. DE MEIJERE 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 1 views

Nazarov Cyclization of Bis ([2.2]paracyclophane-1,9-dienyl) Ketone: First Synthesis of a Bis([2.2]paracyclophane)-Anellated Cyclopenta-1,4-diene. -The anellated cyclopentanone derivatives (II) and (III) can be obtained by Nazarov cyclization of the ketone (I). (III) is successfully transformed into

Synthesis and Diels-Alder Reactions of 1
Synthesis and Diels-Alder Reactions of 1,2-Dimethylene- and 1,2,9,10-Tetramethylene[2.2]paracyclophane: New Routes to Bridge-Anellated [2.2]Paracyclophanedienes
✍ König, Burkhard ;Meijere, Armin De 📂 Article 📅 1992 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 472 KB

## Abstract The title compounds 8 and 1 have been synthesized in three steps each from 1,2‐dibromo[2.2]paracyclophan‐1‐ene (2) and 1,2,9,10‐tetrabromo[2.2]paracyclophane‐1,9‐diene (4), respectively. Copper‐mediated coupling of vinyl bromides 2 and 4 with methyl‐ and phenylmagnesium bromide gives su