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ChemInform Abstract: Synthesis of Bis[1,2]dithiolo[1,4]thiazines and a [1,2]Dithiolo[1,4]thiazine from Tertiary Diisopropylamines.

✍ Scribed by Charles W. Rees; Andrew J. P. White; David J. Williams; Oleg A. Rakitin; Lidia S. Konstantinova; Carlos F. Marcos; Tomas Torroba


Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Bis[1,2]dithiolo[3,
✍ Carlos F. Marcos; Oleg A. Rakitin; Charles W. Rees; Tomas Torroba; Andrew J. P. πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB

Bis [1,2]dithiolo [3,4-b][4',3'-e][1,4]thiazine-3,5-dione, a Planar 1,4-Thiazine. -Reaction of N-benzyldiisopropylamine (I) with S 2 Cl 2 gives N-benzyl-bisthiolothiazine (II) with typically folded structure. Debenzylation of (II) results in a dramatic flattening of the molecule structure giving th