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Selective Synthesis of Bis[1,2]dithiolo[1,4]thiazines from 4-Isopropylamino-5-chloro-1,2-dithiole-3-ones.

✍ Scribed by Lidia S. Konstantinova; Andrej A. Berezin; Kirill A. Lysov; Oleg A. Rakitin

Publisher
John Wiley and Sons
Year
2007
Weight
32 KB
Volume
38
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Bis[1,2]dithiolo[3,
ChemInform Abstract: Bis[1,2]dithiolo[3,4-b][4β€²,3β€²-e][1,4]thiazine-3,5-dione, a Planar 1,4-Thiazine.
✍ Carlos F. Marcos; Oleg A. Rakitin; Charles W. Rees; Tomas Torroba; Andrew J. P. πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB

Bis [1,2]dithiolo [3,4-b][4',3'-e][1,4]thiazine-3,5-dione, a Planar 1,4-Thiazine. -Reaction of N-benzyldiisopropylamine (I) with S 2 Cl 2 gives N-benzyl-bisthiolothiazine (II) with typically folded structure. Debenzylation of (II) results in a dramatic flattening of the molecule structure giving th