ChemInform Abstract: Kinetics and Mechanism of the Oxidation of Organic Sulfides by Pyridinium Hydrobromide Perbromide.
โ Scribed by V. K. VYAS; N. JALANI; S. KOTHARI; K. K. BANERJI
- Book ID
- 112041936
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 25 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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๐ SIMILAR VOLUMES
The oxidation of several monosubstituted phenoxyacetic acids by pyridinium hydrobromide perbromide (PHPB) was studied in aqueous acetic acid. The reaction is first order with respect to PHPB. Michaelis-Mententype kinetics are observed with respect to phenoxyacetic acids. The oxidation of [2,2-\*H,]p
Kinetics and Mechanism of the Oxidation of Organic Sulfides by Bis(2,2' -bipyridyl)copper(II) Permanganate. -The H+-catalyzed oxidation of sulfides to sulfoxides using the title oxidant (BBCP) is found to be first order with respect to BBCP. Michaelis-Menten type kinetics are observed for the sulfi