Kinetics and mechanism of oxidation of phosphorus oxyacids by pyridinium hydrobromide perbromide
β Scribed by Seema Varshney; Pradeep K. Sharma; Kalyan K. Banerji
- Book ID
- 112907657
- Publisher
- Indian Academy of Sciences,Royal Society of Chemistry
- Year
- 1992
- Tongue
- English
- Weight
- 354 KB
- Volume
- 104
- Category
- Article
- ISSN
- 0253-4134
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π SIMILAR VOLUMES
The oxidation of several monosubstituted phenoxyacetic acids by pyridinium hydrobromide perbromide (PHPB) was studied in aqueous acetic acid. The reaction is first order with respect to PHPB. Michaelis-Mententype kinetics are observed with respect to phenoxyacetic acids. The oxidation of [2,2-\*H,]p
The oxidation of lower oxyacids of phosphorus by hexamethylenetetramine bromine (HABR) in glacial acetic acid resulted in the formation of corresponding oxyacids with phosphorus in a higher oxidation state. The reaction exhibited stoichiometry. The reaction 2 : 1 is first order with respect to HABR.