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Kinetics and mechanism of the oxidation of diols by pyridinium hydrobromide perbromide

โœ Scribed by Dipti Mathur; Pradeep K Sharma; Kalyan K Banerji

Book ID
112917969
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1995
Tongue
English
Weight
388 KB
Volume
107
Category
Article
ISSN
0253-4134

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The oxidation of several monosubstituted phenoxyacetic acids by pyridinium hydrobromide perbromide (PHPB) was studied in aqueous acetic acid. The reaction is first order with respect to PHPB. Michaelis-Mententype kinetics are observed with respect to phenoxyacetic acids. The oxidation of [2,2-\*H,]p

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The kinetics of oxidation of four vicinal diols, four nonvicinal diols, and one of their monoethers by pyridinium bromochromate (PBC) have been studied in dimethyl sulfoxide. The main product of oxidation is the corresponding hydroxyaldehyde. The reaction is first-order with respect to each the diol