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ChemInform Abstract: Highly Enantioselective One-Pot, Three-Component Mannich-Type Reaction Catalyzed by an N,N′-Dioxide—Scandium(III) Complex.

✍ Scribed by Shikui Chen; Zongrui Hou; Yin Zhu; Jing Wang; Lili Lin; Xiaohua Liu; Xiaoming Feng

Publisher
John Wiley and Sons
Year
2009
Weight
27 KB
Volume
40
Category
Article
ISSN
0931-7597

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Highly Enantioselective One-Pot, Three-C
Highly Enantioselective One-Pot, Three-Component Mannich-type Reaction Catalyzed by an N,N′-Dioxide–Scandium(III) Complex
✍ Shikui Chen; Zongrui Hou; Yin Zhu; Jing Wang; Lili Lin; Xiaohua Liu; Xiaoming Fe 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 192 KB 👁 1 views

## Abstract **Mild‐mannered Mannich reaction**: Highly enantioselective one‐pot, three‐component Mannich‐type reaction of aldehydes, 2‐aminophenol, and ketene silyl acetal with 5 mol % of a __C__~__2__~‐symmetric __N__,__N__′‐dioxide‐based scandium(III) triflate (2:1) complex as the catalyst was ac