ChemInform Abstract: Highly Enantioselective Aza-Ene-Type Reaction Catalyzed by Chiral N,N′-Dioxide-Nickel(II) Complex.
✍ Scribed by Ke Zheng; Xiaohua Liu; Jiannan Zhao; Yang Yang; Lili Lin; Xiaoming Feng
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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## Abstract **Mild‐mannered Mannich reaction**: Highly enantioselective one‐pot, three‐component Mannich‐type reaction of aldehydes, 2‐aminophenol, and ketene silyl acetal with 5 mol % of a __C__~__2__~‐symmetric __N__,__N__′‐dioxide‐based scandium(III) triflate (2:1) complex as the catalyst was ac