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ChemInform Abstract: Enantioselective Three-Component Kabachnik—Fields Reaction Catalyzed by Chiral Scandium(III)—N,N′-Dioxide Complexes.

✍ Scribed by Xin Zhou; Deju Shang; Qi Zhang; Lili Lin; Xiaohua Liu; Xiaoming Feng

Publisher
John Wiley and Sons
Year
2009
Weight
28 KB
Volume
40
Category
Article
ISSN
0931-7597

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## Abstract **Mild‐mannered Mannich reaction**: Highly enantioselective one‐pot, three‐component Mannich‐type reaction of aldehydes, 2‐aminophenol, and ketene silyl acetal with 5 mol % of a __C__~__2__~‐symmetric __N__,__N__′‐dioxide‐based scandium(III) triflate (2:1) complex as the catalyst was ac