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ChemInform Abstract: First Highly Regio- and Diastereoselective [3 + 2] Cycloaddition of Chiral Nonracemic Alkenyl Fischer Carbene Complexes with Diazomethane Derivatives: Preparation and Synthetic Applications of Enantiomerically Pure Δ2-Pyrazolines.

✍ Scribed by Jose Barluenga; Felix Fernandez-Mari; Argimiro L. Viado; Enrique Aguilar; Bernardo Olano; Santiago Garcia-Granda; Carmen Moya-Rubiera

Publisher: John Wiley and Sons
Year: 2010
Weight: 46 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199928151

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A new procedure for the synthesis of 1,3,4-trisubstituted and 1,4-disubstituted pyrrolidin-2-one derivatives in an enantioselective fashion is reported. The 1,3-dipolar cycloaddition of (AE)menthol and (À)-8-phenylmenthol derived Fischer alkoxy alkenyl carbene complexes with in situ generated functi

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