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ChemInform Abstract: Fine Tuning of Dirhodium(II) Complexes: Exploring the Axial Modification

โœ Scribed by Alexandre F. Trindade; Jaime A. S. Coelho; Carlos A. M. Afonso; Luis F. Veiros; Pedro M. P. Gois


Book ID
112043800
Publisher
John Wiley and Sons
Year
2012
Weight
18 KB
Volume
43
Category
Article
ISSN
0931-7597

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Novel Unsymmetrical ortho-Metalated Dirhodium(II) Catalysts: trans Influence of the Axial Ligand. -The Rh-catalyzed decomposition of the diazoketone (I) resulting in formation of the bicyclic ketone (II) is investigated in detail. The inductive effect of X axial groups which are transmitted through