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Tuning the Reactivity of Dirhodium(II) Complexes with Axial N-Heterocyclic Carbene Ligands: The Arylation of Aldehydes.

✍ Scribed by Pedro M. P. Gois; Alexandre F. Trindade; Luis F. Veiros; Vania Andre; M. Teresa Duarte; Carlos A. M. Afonso; Stephen Caddick; F. Geoffrey N. Cloke


Publisher
John Wiley and Sons
Year
2007
Weight
34 KB
Volume
38
Category
Article
ISSN
0931-7597

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✍ Alberto Acosta-RamΓ­rez; David Morales-Morales; Juan Manuel Serrano-Becerra; Alma πŸ“‚ Article πŸ“… 2008 πŸ› Elsevier Science 🌐 English βš– 245 KB

The catalytic isomerization of 2-methyl-3-butenenitrile (2M3BN) was performed in the presence of Ni(0) with N-heterocyclic carbene (NHC) ligands. On using bulky aromatic substituents on the NHC nitrogen atoms, the isomerization reaction proceeded at room temperature within 15 min: a total conversion