Novel Unsymmetrical ortho-Metalated Dirhodium(II) Catalysts: trans Influence of the Axial Ligand. -The Rh-catalyzed decomposition of the diazoketone (I) resulting in formation of the bicyclic ketone (II) is investigated in detail. The inductive effect of X axial groups which are transmitted through
ChemInform Abstract: Axial Coordination of NHC Ligands on Dirhodium(II) Complexes: Generation of a New Family of Catalysts.
β Scribed by Alexandre F. Trindade; Pedro M. P. Gois; Luis F. Veiros; Vania Andre; M. Teresa Duarte; Carlos A. M. Afonso; Stephen Caddick; F. Geoffrey N. Cloke
- Book ID
- 102020073
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 40 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
β¦ Synopsis
Abstract
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable via the βReferencesβ option.
π SIMILAR VOLUMES
Chiral Ο-Complexes of Heterocycles with Transition Metals: A Versatile New Family of Nucleophilic Catalysts. -The title complex (I) is shown to provide greater than 100-fold acceleration for a series of chemical transformations. The optically active complex (II) allows the kinetic resolution of alco