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ChemInform Abstract: Chiral π-Complexes of Heterocycles with Transition Metals: A Versatile New Family of Nucleophilic Catalysts.

✍ Scribed by J. C. RUBLE; G. C. FU

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199709033

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✦ Synopsis

Chiral π-Complexes of Heterocycles with Transition Metals: A Versatile New Family of Nucleophilic Catalysts. -The title complex (I) is shown to provide greater than 100-fold acceleration for a series of chemical transformations. The optically active complex (II) allows the kinetic resolution of alcohol (IX) with selectivity factors being the highest that have been reported for the non-enzymatic acylation of this substrate. -(RUBLE,

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