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ChemInform Abstract: Extremely High Enantioselective Redox Reaction of Ketones and Alcohols Catalyzed by RuCl2(PPh3)(oxazolinylferrocenylphosphine).

✍ Scribed by Yoshiaki Nishibayashi; Izuru Takei; Sakae Uemura; Masanobu Hidai

Book ID: 101884254
Publisher: John Wiley and Sons
Year: 2010
Weight: 36 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199939031

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## Abstract A Ru(II)—dichlorobipyridine complex (Ia) efficiently catalyzes the redox isomerization of terminal and internal allylic alcohols to give the corresponding ketones, e.g. (III), (V) or (VII), in high to excellent conversion.