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ChemInform Abstract: Enantioselective Reduction of Ketones with Borane Catalyzed by Cyclic . beta.-Amino Alcohols Prepared from Proline.

✍ Scribed by A. S. DEMIR; I. MECITOGLU; C. TANYELI; V. GUELBEYAZ


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
28
Category
Article
ISSN
0931-7597

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Asymmetric Reduction of Ketoxime Ethers to Optically Active O-Substituted Hydroxylamines with Reagents Prepared from Borane and Chiral Amino Alcohols. -The reduction in the presence of norephedrine is an efficient method to prepare chiral O-substituted hydroxylamines. However, O-Tbs and O-tBu subst