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Extremely High Enantioselective Redox Reaction of Ketones and Alcohols Catalyzed by RuCl 2 (PPh 3 )(oxazolinylferrocenylphosphine)

✍ Scribed by Nishibayashi, Yoshiaki; Takei, Izuru; Uemura, Sakae; Hidai, Masanobu


Book ID
120595292
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
67 KB
Volume
18
Category
Article
ISSN
0276-7333

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Atom-Transfer Radical Addition (ATRA) an
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## Abstract A new catalytic procedure for atom‐transfer radical addition (ATRA) and cyclization (ATRC) reactions is described. The combination of the ruthenium(III) complex [RuCl~2~Cp\*(PPh~3~)] (Cp\*: pentamethylcyclopentadienyl) with magnesium allows these reactions to be performed under mild con