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Atom-Transfer Radical Addition (ATRA) and Cyclization (ATRC) Reactions Catalyzed by a Mixture of [RuCl2Cp*(PPh3)] and Magnesium.

โœ Scribed by Katrin Thommes; Burcak Icli; Rosario Scopelliti; Kay Severin


Publisher
John Wiley and Sons
Year
2007
Weight
48 KB
Volume
38
Category
Article
ISSN
0931-7597

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Atom-Transfer Radical Addition (ATRA) an
โœ Katrin Thommes; Burรงak Iรงli; Rosario Scopelliti; Kay Severin ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 192 KB ๐Ÿ‘ 1 views

## Abstract A new catalytic procedure for atomโ€transfer radical addition (ATRA) and cyclization (ATRC) reactions is described. The combination of the ruthenium(III) complex [RuCl~2~Cp\*(PPh~3~)] (Cp\*: pentamethylcyclopentadienyl) with magnesium allows these reactions to be performed under mild con

Atom-Transfer Radical Addition Reactions
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## Abstract Kinetic and spectroscopic analyses were performed to gain information about the mechanism of atomโ€transfer radical reactions catalyzed by the complexes [RuCl~2~Cp\*(PPh~3~)] and [RuClCp\*(PPh~3~)~2~] (Cp\*=pentamethylcyclopentadienyl), in the presence and in the absence of the reducing

ChemInform Abstract: Atom Transfer Radic
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a โ€œFull Textโ€ option. The original article is trackable v