## Abstract A new catalytic procedure for atomโtransfer radical addition (ATRA) and cyclization (ATRC) reactions is described. The combination of the ruthenium(III) complex [RuCl~2~Cp\*(PPh~3~)] (Cp\*: pentamethylcyclopentadienyl) with magnesium allows these reactions to be performed under mild con
Atom-Transfer Radical Addition (ATRA) and Cyclization (ATRC) Reactions Catalyzed by a Mixture of [RuCl2Cp*(PPh3)] and Magnesium.
โ Scribed by Katrin Thommes; Burcak Icli; Rosario Scopelliti; Kay Severin
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 48 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Kinetic and spectroscopic analyses were performed to gain information about the mechanism of atomโtransfer radical reactions catalyzed by the complexes [RuCl~2~Cp\*(PPh~3~)] and [RuClCp\*(PPh~3~)~2~] (Cp\*=pentamethylcyclopentadienyl), in the presence and in the absence of the reducing
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