The atom transfer radical polymerization (ATRP) of styrene has been studied using complexes of copper carboxylates. Compared with systems employing copper halides as the catalyst, the use of copper carboxylates resulted in faster polymerization rates and higher polydispersities. A ligand (dNbpy) to
ChemInform Abstract: Atom Transfer Radical Addition and Polymerization Reactions Catalyzed by ppm Amounts of Copper Complexes
✍ Scribed by Tomislav Pintauer; Krzysztof Matyjaszewski
- Publisher
- John Wiley and Sons
- Year
- 2008
- Weight
- 15 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract Kinetic and spectroscopic analyses were performed to gain information about the mechanism of atom‐transfer radical reactions catalyzed by the complexes [RuCl~2~Cp\*(PPh~3~)] and [RuClCp\*(PPh~3~)~2~] (Cp\*=pentamethylcyclopentadienyl), in the presence and in the absence of the reducing
## Abstract Copper‐mediated atom transfer radical polymerization (ATRP) is versatile for living polymerizations of a wide range of monomers, but ATRP of vinyl acetate (VAc) remains challenging due to the low homolytic cleavage activity of the carbon‐halide bond of the dormant poly(vinyl acetate) (P