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ChemInform Abstract: Copper-Catalyzed Atom Transfer Radical Addition (ATRA) and Cyclization (ATRC) Reactions in the Presence of Reducing Agents

✍ Scribed by William T. Eckenhoff; Tomislav Pintauer

Publisher
John Wiley and Sons
Year
2011
Weight
19 KB
Volume
42
Category
Article
ISSN
0931-7597

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Atom-Transfer Radical Addition (ATRA) an
Atom-Transfer Radical Addition (ATRA) and Cyclization (ATRC) Reactions Catalyzed by a Mixture of [RuCl2Cp*(PPh3)] and Magnesium
✍ Katrin Thommes; BurΓ§ak IΓ§li; Rosario Scopelliti; Kay Severin πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 192 KB πŸ‘ 1 views

## Abstract A new catalytic procedure for atom‐transfer radical addition (ATRA) and cyclization (ATRC) reactions is described. The combination of the ruthenium(III) complex [RuCl~2~Cp\*(PPh~3~)] (Cp\*: pentamethylcyclopentadienyl) with magnesium allows these reactions to be performed under mild con