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ChemInform Abstract: Epoxide Derivatives of Pipecolic Acid and Proline Are Inhibitors of Pipecolate Oxidase.

โœ Scribed by B. HO; T. M. ZABRISKIE

Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
29
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Asymmetric Synthesi
ChemInform Abstract: Asymmetric Synthesis of Unsaturated Pipecolic Acid Derivatives.
โœ C. AGAMI; D. BIHAN; R. MORGENTIN; C. PUCHOT-KADOURI ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 32 KB ๐Ÿ‘ 1 views

The synthesis of two enantiopure pipecolic acid esters (VI) and (XIII) is reported. Key steps are the intramolecular addition of allyl silane on an iminium double bond, generated via reaction of chiral ฮฒ-amino alcohols (I) and (VII), with glyoxal (II).