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ChemInform Abstract: Efficient Synthesis of β-Hydroxy Ketones from Allylic Alcohols by Catalytic Formation of Ruthenium Enolates.

✍ Scribed by Agnieszka Bartoszewicz; Madeleine Livendahl; Belen Martin-Matute

Publisher
John Wiley and Sons
Year
2009
Weight
44 KB
Volume
40
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.

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## Abstract A Ru(II)—dichlorobipyridine complex (Ia) efficiently catalyzes the redox isomerization of terminal and internal allylic alcohols to give the corresponding ketones, e.g. (III), (V) or (VII), in high to excellent conversion.