## Abstract Reactions of aldehyde arylhydrazones (**1**) with nitric oxide in the presence of trace oxygen gave exclusively (__E__)βC(1β²)βnitrohydrazones (**2**) in high yield. The structure of products was confirmed by NMR, IR, MS and Xβray crystallography. The reaction is assumed to be initiated
ChemInform Abstract: Configuration-Specific Reaction of Nitric Oxide with Aldehyde Arylhydrazones.
β Scribed by Desuo Yang; Haiyun Zhu; Yaning Guo; Longmin Wu
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 23 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
The unexpected reaction leads exclusively to (E)βnitrohydrazones (II); azoβcompounds are not obtained.
π SIMILAR VOLUMES
Reaction of Nitric Oxide with Amines. -NO and NO/O2, respectively, are found to be useful reagents for the aromatization of Hantzsch dihydropyridines (β (II)) and deamination of aromatic amines (β (VI)). -
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