## Abstract Reactions of aldehyde arylhydrazones (**1**) with nitric oxide in the presence of trace oxygen gave exclusively (__E__)βC(1β²)βnitrohydrazones (**2**) in high yield. The structure of products was confirmed by NMR, IR, MS and Xβray crystallography. The reaction is assumed to be initiated
A Novel Reaction of Ketone Arylhydrazones with Nitric Oxide.
β Scribed by Desuo Yang; Liandi Lei; Zhongquan Liu; Longmin Wu
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 105 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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## Abstract The unexpected reaction leads exclusively to (E)βnitrohydrazones (II); azoβcompounds are not obtained.
Reaction of Nitric Oxide with Amines. -NO and NO/O2, respectively, are found to be useful reagents for the aromatization of Hantzsch dihydropyridines (β (II)) and deamination of aromatic amines (β (VI)). -
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