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ChemInform Abstract: Complex Allylation by the Direct Cross-Coupling of Imines with Unactivated Allylic Alcohols.

✍ Scribed by Masayuki Takahashi; Martin McLaughlin; Glenn C. Micalizio

Publisher
John Wiley and Sons
Year
2009
Weight
42 KB
Volume
40
Category
Article
ISSN
0931-7597

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Complex Allylation by the Direct Cross-C
Complex Allylation by the Direct Cross-Coupling of Imines with Unactivated Allylic Alcohols
✍ Masayuki Takahashi; Martin McLaughlin; Glennβ€…C. Micalizio πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 408 KB πŸ‘ 1 views

## Abstract **Regioselective, stereoselective**: The convergent coupling of allylic alcohols with imines to deliver stereodefined homoallylic amines is described (see scheme). The process proceeds with net allylic transposition without the intermediacy of allylic organometallic reagents. Two stereo

ChemInform Abstract: Stereoselective Phe
ChemInform Abstract: Stereoselective Phenylation of Allylic Alcohol Derivatives by Palladium-Catalyzed Cross-Coupling with Hypervalent Silicon Complexes.
✍ M.-R. BRESCIA; P. DESHONG πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 34 KB

Stereoselective Phenylation of Allylic Alcohol Derivatives by Palladium-Catalyzed Cross-Coupling with Hypervalent Silicon Complexes. -The silicate complex (II) is found to be a highly effective reagent for the phenylation of allylic benzoates. The phenylation is completely stereoselective and occur